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In the mid-22nd century, the Earth ship Enterprise is launched under the command of Captain Jonathan Archer. When the crew rescues an alien from a crashed spaceship, Earth gets its first look at the alien's race - the Klingons. Archer and his crew must walk a fine line as they attempt to communicate with the Klingon pilot, whose language is completely unknown, and whose homeworld wants him back. Is this the beginning of friendship...or interstellar war?

After previously offending the Kreetassans, Enterprise attempts to make a better second impression, only to upset the alien race once again. A frustrated Captain Archer returns from the planet only to be further upset to find that his dog Porthos, has been affected by a pathogen native to the world. While Phlox works around the clock treating Porthos, Archer stands vigil in sickbay, experiencing first-hand the quirky everyday life of his Denobulan Doctor.

Almost the entire crew is left unconscious when four Ferengi pirates raid Enterprise. A still conscious Trip is the only one who can get rid of them.

While Enterprise is visiting Earth, Phlox is abducted by the Klingons and forced to research a cure for a virus destined to wipe out the race. Reed is tapped by a secret agency and ordered to betray Archer. Trip transfers to the Columbia.

After an attack by Osaarian pirates, Enterprise follows them to a mysterious sphere.

T'Pol and Archer confront the Syrrannites and meet T'Pau who denies the embassy bombing. Archer, who has Surak's essence, is asked to help. V'Las threatens Enterprise to make sure an attack on the Syrrannites isn't witnessed.

Archer decides he should pilot a kamikaze shuttle to destroy the Xindi weapon. Temporal agent Daniels urges him to reconsider.

Enterprise escorts Tellarites to peace talks with Andorians. While transporting they rescue Andorians and say the Tellarites attacked them. Enterprise is soon attacked by an Andorian ship, and Archer must prove who is responsible.

After a Klingon ship is attacked, it's discovered the imprisoned Dr. Soong's genetically enhanced humans are responsible. Archer takes him to prevent a war.

The men of Enterprise fall under the seductive control of three Orion women. Trip is the only male member of the crew not to succumb to the women.

After exploring an uninhabited planet, Captain Archer is taken prisoner by a Tellarite bounty hunter who was hired by the Klingons to return Archer to Qo'noS.

Enterprise discovers a comet which contains the very rare element eisilium. Then unexpectedly a Vulcan ship arrives. Captain Vanik tells they're interested in human behavior.

Archer and Trip are accused of smuggling and sent to the penal colony Canamar. While Enterprise manages to negotiate their release, a mutiny breaks out on the prison ship.

On the first anniversary of her assignment to Enterprise, T'Pol tells Archer and Trip about the first contact between humans and Vulcans, which involves three Vulcans becoming stranded in the town of Carbon Creek, Pennsylvania in 1957.

Archer and T'Pol travel back in time to Detroit in 2004 to stop three Xindi-Reptilians from constructing a bioweapon.

Captain Archer is asked to negotiate between the Andorians and Vulcans who are fighting over a small planet.

Enterprise is taken over by religious zealots who want to use the ship in a war against heretics.

T'Pol finds unusual neutrino readings on a planet with a preindustrial society.

Enterprise encounters a hyper-giant star. While there, they make first contact with the Vissians, a technologically sophisticated race with three genders. While making quick friends, and eagerly learning about the advanced technology, Trip gets curious about the Vissians third gender, known as the Cogenitor, who is crucial in the Vissian reproductive process. Against the wishes of the Vissians, Trip befriends the Cogenitor and encourages it to defy its cultural boundaries, which the Vissians are made aware of, and are angered by.

Enterprise has a group of aliens watching a stellar phenomenon on board. When the ship is miraculously saved from blowing up, crewman Daniels has an important message for Archer.

The Augments are on their way to Cold Station 12, where Augments embryos are kept.

While the Reptilians force Hoshi to decipher a launch code, the Primates, Arboreals and Archer think of a way to stop the Xindi weapon.

Dr. Emory Erickson comes aboard to supposedly conduct tests for subquantum transportation. However, he seems to have a different agenda.

Captain Archer has been returned to Enterprise by the Xindi council awaiting a hearing. But after a heavy attack by the Reptilians, Enterprise is stranded without a functional warp drive. They meet another ship in trouble because of space anomalies. The ship's captain isn't willing to trade in their warp coil and Archer must make a tough decision. Meanwhile T'Pol is having some strange sensations and can't control her emotions.

Trip's shuttlepod is shot down by a hostile race and is forced to land on a deserted moon. There he must team up with the alien who shot him down in order to find a way back to Enterprise.