Caitlyn Jenner will pay an $800,000 settlement to multiple members of the family involved in her February 2015 car accident on the Pacific Coast Highway in Malibu.

Jenner, 68, will pay $100,000 to both music industry vet Peter Wolf-Millesi and his wife Lea Wolf-Millesi — they sued Jenner in late 2015 for injuries they allegedly suffered after Kim Howe’s Lexus struck their vehicle — according to documents obtained by The Blast. They blamed Jenner for “serious injuries to their bodies” and “great physical and mental pain and suffering” stemming from the crash.

Lea’s mother, Elga Maurer — who was in the vehicle at the time of...