- Identical twin brother of Thomas Chambers.
- Was a nationally ranked trampolinist along with his brother, Thomas.
- He went to high school with Charlotte Arnold, who plays Holly J. Sinclair.
- Munro originally auditioned for the part of 'Drew' before getting the role of 'Eli' on Degrassi.
- His uncle is Colin Mochrie, from the American version of Whose Line Is It Anyway?.
- Munro is 2 minutes younger than his twin brother Thomas.
- His first 'acting' job was a McDonald's commercial.
- He is best friends with Justin Kelly and Demetrius Joyette, his co stars from The Latest Buzz.
- Munro was one of the presenters for the 2011 Much Music Video Awards.
- Attended Newmarket High School, in Newmarket, Ontario.
- His mother is French-Canadian. Her family is from New Brunswick.
- Munro Chambers performed the song "Songbirds" with Danielle Belanger at the Newmarket Theatre.
- His parents' names are Scott and Lorette.
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