- Come All You Fair and Tender LadiesTraditional folk songSung a cappella by Emmy Rossum
- The Ballad of Barbara AllenPerformed a cappela by Janet McTeer and Emmy Rossum
- Conversation with DeathTraditional folk song
- Down in a Willow GardenTraditional folk song
- Johnnie ScotTraditional folk song
- Leather BreechesTraditional folk song
- Lord RandallTraditional folk songSung a cappella by Emmy Rossum
- Lord Thomas & Fair EllinorTraditional folk song
- Matty GrovesTraditional folk songSung a cappella by Emmy Rossum and Janet McTeer
- Old Joe ClarkTraditional folk song
- Pretty SaroTraditional folk songPlayed on violin by Muse Watson and sung by Iris DeMentIris DeMent appears courtesy of Warner Bros. Records, Inc.
- Sally GoodinTraditional folk songPlayed on violin by Josh Goforth and
- Silk Merchant's DaughterTraditional folk song
- Single GirlTraditional folk songSung a cappella by Pat Carroll and Janet McTeer
- Soldier's JoyTraditional folk song
- The Trooper and the MaidTraditional folk song
- The Two SistersTraditional folk songSung a cappella by Emmy Rossum
- Young HuntingTraditional folk song
- When the Mountains CryWritten by David Mansfield and Tom RussellPublished by Jocada Music (BMI) and Frontera Music (ASCAP)Administered by Bug Music, Inc.
- Pickin' That Thang (Dr. Joe)Written and Performed by Taj MahalPublished by Sony Music Publishing
- Barbara AllenTraditional folk songMusic Arranged and Performed by David MansfieldPerformed by Emmylou Harris during the end credits
- When Love Is NewWritten by Dolly PartonPerformed by Dolly Parton and Emmy Rossum
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