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- An eccentric genius forms a team of super-geniuses who are tasked with being the last line of defense against complicated threats to National Security.
- A 10-year-old boy is trapped in a rockslide/sinkhole near the beach. The team must find a way to rescue him before the rising tide fills it up with water.
- Sylvester is seriously injured when he accidentally triggers an explosive device during an investigation, and Team Scorpion searches for who is responsible.
- The team tries to help Ralph when he is taken by the FBI for questioning after his web game play unintentionally reveals a CIA safe house's location.
- The team works with an injured former Secret Service agent, attempting to restore his memories to avoid a nuclear launch from a secret US silo.
- Team Scorpion goes undercover on a cruise ship to locate and disable deadly stolen rockets. Meanwhile, as Valentine's Day approaches, Toby and Happy help Ralph, who is in the throes of his first crush.
- A tech billionaire hires the team to rescue his kidnapped daughter. Meanwhile, feelings are hurt when Walter gives an interview and fails to acknowledge the other members of the team.
- When a conflict in Eastern Europe threatens to escalate, Team Scorpion is called on to help facilitate secret peace talks to prevent World War III.
- While on a mission to save lost hikers, Team Scorpion's helicopter crashes, igniting a massive wildfire that quickly closes in on them. Also, Sylvester must help their injured pilot who is unable to make it to safer ground.
- To protect a key witness who is en route to testifying against a deadly drug cartel, Team Scorpion takes her on the run, with the cartel hot on their heels.
- Walter learns Cabe's long-hidden secret regarding the Baghdad mission and it threatens to tear Team Scorpion apart. Meanwhile, Ralph puts his life in danger to help the team.
- Team Scorpion is torn apart and uncertain about their future as a unit, but they are forced to come together to save Walter's life when his car teeters on the side of a cliff.
- The team tries to stop a runaway train that Paige and Ralph are on.
- Megan's condition gets worse. Walter starts to get frustrated about not being able to help her and in Walter's crazy quest for investors, the CIA appears in the garage with the promise of a big payday.
- As Megan's condition worsens, the team gathers at the hospital. As they arrive, they find a pathogen has infected the hospital threatening all of their lives.
- The Scorpion team goes undercover at a college to discover who is holding the Federal Reserve for ransom. Walter tries to help Ray, while Paige tries to get Walter to express grief about Megan.
- Team Scorpion is blackmailed to break into the United Nations to assist in the assassination of a menacing arms dealer. Also, Sylvester makes a bold move to protect Megan's wishes.
- It's Christmas Eve, and Team Scorpion must prevent a catastrophe when torrential rains create a large crack in a dam. They fight to save an entire town from the threat of being wiped out in its wake.
- In order to save a United States Special Forces unit from certain death, the Scorpion Team must get through the very low temperatures of Antarctica to connect to a satellite in order to save the soldiers. Toby risks his life to save Happy.
- Sylvester comes face to face with his estranged father, a retired colonel, who asks Team Scorpion for help when he believes that a dictator in Africa has uncovered a deadly World War II-era weapon of mass destruction and intends to use it.
- Team Scorpion is tasked with helping NASA's top secret rocket launch, but they must sabotage their own mission when Walter's date from the previous night has a bomb strapped to her chest.
- While Team Scorpion works to stop an influx of drugs being smuggled into the country via drones, Walter gives Happy and Toby an ultimatum on their new relationship. Penn Jillette guest stars.
- When a powerful earthquake hits LA, Team Scorpion must prevent a pinched gas line from causing a massive explosion.
- After Sylvester scores big on THE PRICE IS RIGHT, Team Scorpion must infiltrate a high-end car smuggling operation about to ship bioweapons to South America
- Scorpion is sent on a secret mission to Djibouti, Africa. Cabe is captured. The Team must save him. While Walter has suspicions about the purpose of the mission and concerns over Paige's interest in new Homeland protégé, Tim Armstrong.